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Arylation/Intramolecular Conjugate Addition of 1,6-Enynes Enabled by Manganese(I)-Catalyzed C-H Bond Activation 期刊论文

编号：

902504ee-3fea-4308-bc93-c09810414718
作者：

Tan, YunXuan#^[1]Liu, XingYu#^[1,2]Zhao, YiShuang^[1];Tian, Ping*^[1,3]Lin, GuoQiang*^[1,2,3]
语种：

英文
期刊：

ORGANIC LETTERS ISSN：1523-7060 2019 年 21 卷 1 期 (5 - 9) ; JAN 4
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摘要：

An arylation/intramolecular conjugate addition of cyclohexadienone-containing 1,6-enynes has been established through initiation by manganese(I)-catalyzed C-H bond activation. This tandem reaction involved unusual E/Z-isomerized alkenyl-Mn intermediates and proceeded smoothly with high chemoselectivities and perfect atom economy. The cyclization products could be further transformed to various structures. Mechanistic studies suggested that cleavage of the C-H bond was involved in the turnover-limiting step, and a manganese carbene anion intermediate was proposed to explain such an E/Z isomerization process.
推荐引用方式
GB/T 7714：

Tan Yun-Xuan,Liu Xing-Yu,Zhao Yi-Shuang, et al. Arylation/Intramolecular Conjugate Addition of 1,6-Enynes Enabled by Manganese(I)-Catalyzed C-H Bond Activation [J].ORGANIC LETTERS,2019,21(1):5-9.
APA：

Tan Yun-Xuan,Liu Xing-Yu,Zhao Yi-Shuang,Tian Ping,&Lin Guo-Qiang.(2019).Arylation/Intramolecular Conjugate Addition of 1,6-Enynes Enabled by Manganese(I)-Catalyzed C-H Bond Activation .ORGANIC LETTERS,21(1):5-9.
MLA：

Tan Yun-Xuan, et al. "Arylation/Intramolecular Conjugate Addition of 1,6-Enynes Enabled by Manganese(I)-Catalyzed C-H Bond Activation" .ORGANIC LETTERS 21,1(2019):5-9.
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