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Synthesis and Characterization of a Pentiptycene-Derived Dual Oligoparaphenylene Nanohoop 期刊论文

编号：

854a1b68-9bfb-4dae-a013-96da702bd225
作者：

Xu, Wei#^[1,2]Yang, XiaoDi^[3]Fan, XiangBing^[1,2];Wang, Xin^[1,2];Tung, ChenHo^[1,2];Wu, LiZhu^[1,2];Cong, Huan*^[1,2]
语种：

英文
期刊：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION ISSN：1433-7851 2019 年 58 卷 12 期 (3943 - 3947) ; MAR 18
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关键词：

Diels-Alder cycloaddition macrocycles nanohoops oligoparaphenylenes pentiptycenes
摘要：

Structural designs combining oligoparaphenylene-derived nanohoops with other functional organic building blocks should lead to novel molecular architectures with intriguing properties. Herein, we describe the synthesis of a pentiptycene-derived chiral dual nanohoop molecule with key steps including ring expansion through dianthracene cycloreversion and transannular [4+2] cycloaddition across a 64-membered macrocycle. The crystal structure of the nanohoop molecule displays an ordered packing pattern with long-range channels in the solid slate. Furthermore, nonracemizable enantiomers of the nanohoop were obtained through resolution and exhibited promising chiroptical properties.
推荐引用方式
GB/T 7714：

Xu Wei,Yang Xiao-Di,Fan Xiang-Bing, et al. Synthesis and Characterization of a Pentiptycene-Derived Dual Oligoparaphenylene Nanohoop [J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(12):3943-3947.
APA：

Xu Wei,Yang Xiao-Di,Fan Xiang-Bing,Wang Xin,&Cong Huan.(2019).Synthesis and Characterization of a Pentiptycene-Derived Dual Oligoparaphenylene Nanohoop .ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(12):3943-3947.
MLA：

Xu Wei, et al. "Synthesis and Characterization of a Pentiptycene-Derived Dual Oligoparaphenylene Nanohoop" .ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58,12(2019):3943-3947.
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