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Asymmetric Alkenylation of Enones and Imines Enabled by A Highly Efficient Aryl to Vinyl 1,4-Rhodium Migration 期刊论文

编号：

77c7af84-a288-4d20-99b3-c13f85a29357
作者：

Zhang, ShuSheng#^[1]Hu, TianJiao#^[2]Li, MengYao^[2];Song, YiKang^[1];Yang, XiaoDi^[1];Feng, ChenGuo*^[1,2]Lin, GuoQiang*^[1,2]
语种：

英文
期刊：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION ISSN：1433-7851 2019 年 58 卷 11 期 (3387 - 3391) ; MAR 11
收录：
关键词：

alkenylation asymmetric catalysis C-H functionalization metal migration rhodium
摘要：

The asymmetric rhodium-catalyzed alkenylation of enones and imines with arylboronic acids has been developed. A highly controllable aryl to vinyl 1,4-rhodium migration is the key step. Stereodefined vinyl moieties were installed in excellent enantioselectivies for most examined examples. DFT calculations reveal that the driving force of this rhodium migration is a kinetically favored process.
推荐引用方式
GB/T 7714：

Zhang Shu-Sheng,Hu Tian-Jiao,Li Meng-Yao, et al. Asymmetric Alkenylation of Enones and Imines Enabled by A Highly Efficient Aryl to Vinyl 1,4-Rhodium Migration [J].ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(11):3387-3391.
APA：

Zhang Shu-Sheng,Hu Tian-Jiao,Li Meng-Yao,Song Yi-Kang,&Lin Guo-Qiang.(2019).Asymmetric Alkenylation of Enones and Imines Enabled by A Highly Efficient Aryl to Vinyl 1,4-Rhodium Migration .ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(11):3387-3391.
MLA：

Zhang Shu-Sheng, et al. "Asymmetric Alkenylation of Enones and Imines Enabled by A Highly Efficient Aryl to Vinyl 1,4-Rhodium Migration" .ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58,11(2019):3387-3391.
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