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Garsubelone A, the First Dimeric Polycyclic Polyprenylated Acylphloroglucinols with Complicated Heptacyclic Architecture from Garcinia subelliptica  期刊论文  

  • 编号:
    71f02798-037b-4efc-b0dd-536b80a73038
  • 作者:
    Wang, YongLing#[1,2]Ye, YanSong[3,4,5];Fu, WenWei(付文卫)[1,2]Wu, Rong(吴蓉)[1,2]Xiang, Qian[1,2];Lao, YuanZhi(劳远至)[1,2]Yang, JinLing[1,2];Tan, HongSheng(谭红胜)[1,2]Yang, XingWei[3,4];Yang, BaiCan(杨柏灿)[1,2]Xu, HongXi(徐宏喜)*[1,2]Xu, Gang*[3,4]
  • 语种:
    英文
  • 期刊:
    ORGANIC LETTERS ISSN:1523-7060 2019 年 21 卷 5 期 (1534 - 1537) ; MAR 1
  • 收录:
  • 摘要:

    Garsubelone A (1), the first dimeric polycyclic polyprenylated acylphloroglucinols type metabolite featuring a complicated 6/6/6/6/6/6/6 heptacyclic architecture containing 10 stereogenic centers, was isolated from Garcinia subelliptica. Biogenetically, this compound was constructed by the plausible monomeric precursor, garsubelone B (2) and secohyperforin, via a key Diels-Alder cycloaddition to form an unique 2-oxabicyclo[3.3.1]nonane core. Their structures and absolute configurations were determined by comprehensive spectroscopic and X-ray diffraction techniques. The cytotoxic activities of these isolates were also evaluated.

  • 推荐引用方式
    GB/T 7714:
    Wang Yong-Ling,Ye Yan-Song,Fu Wen-Wei, et al. Garsubelone A, the First Dimeric Polycyclic Polyprenylated Acylphloroglucinols with Complicated Heptacyclic Architecture from Garcinia subelliptica [J].ORGANIC LETTERS,2019,21(5):1534-1537.
  • APA:
    Wang Yong-Ling,Ye Yan-Song,Fu Wen-Wei,Wu Rong,&Xu Gang.(2019).Garsubelone A, the First Dimeric Polycyclic Polyprenylated Acylphloroglucinols with Complicated Heptacyclic Architecture from Garcinia subelliptica .ORGANIC LETTERS,21(5):1534-1537.
  • MLA:
    Wang Yong-Ling, et al. "Garsubelone A, the First Dimeric Polycyclic Polyprenylated Acylphloroglucinols with Complicated Heptacyclic Architecture from Garcinia subelliptica" .ORGANIC LETTERS 21,5(2019):1534-1537.
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